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硒化锌（ZnSe）棱镜

ZnSe 在红外元器件窗片透镜以及光谱分析ATR 棱镜领域有着广泛的应用。硒化锌(Zinc Selenide)对于CO2激光器的元器件也是一种良好的选择。在二氧化碳激光器工作的波段10.6 microns附近有着良好的透射率。硒化锌材料是一种黄色透明的多晶材料, 结晶颗粒大小约为70μm, 透光范围0.5-15μm。由化学气相沉积(CVD)方法合成的基本不存在杂质吸收, 散射损失很低。由于对10.6μm波长光的吸收很小, 因此成为制作高功率CO2激光器系统中光学器件的首选材料。 此外在其整个透光波段内, 也是在不同光学系统中所普遍使用的材料。

硒化锌材料对热冲击具有很高的承受能力, 使它成为高功率CO2激光器系统中的zui佳光学材料。硬度只是多光谱级ZnS的2/3, 材质较软易产生划痕, 而且材料折射率较大, 所以需要在其表面镀制高硬度减反射膜来加以保护并获得较高的透过率。在其常用光谱范围内, 散射很低。在用做高功率激光器件时, 需要严格控制材料的体吸收和内部结构缺陷, 并采用zui小破坏程度的抛光技术和zui高光学质量的镀膜工艺。

广泛应用于激光,医学，天文学和红外夜视等领域中。


技术参数：

透射波段范围 :

0.6 to 21.0 um

折射率：

2.4028 at 10.6 um

反射损耗：

29.1% at 10.6 um (2 surfaces)

吸收系数：

0.0005 cm-1at 10.6 um

吸收峰：

45.7 um

dn/dT :

    +61 x 10-6/℃ at 10.6 um at 298K

dn/du = 0 :

5.5 um

密度：

5.27 g/cc

熔点：

1525℃ (see notes below)

导热系数：

18 W m-1 K-1at 298K

热膨胀：

7.1 x 10-6/℃at 273K

硬度 :

Knoop 120 with 50g indenter

比热容量 :

339 J Kg-1K-1

Dielectric Constant :

n/a

Youngs Modulus (E) :

67.2 GPa

Shear Modulus (G) :

n/a

Bulk Modulus (K) :

40 GPa

弹性系数 :

Not Available

Apparent Elastic Limit :

55.1 MPa (8000 psi)

泊松比 :

0.28

Solubility :

0.001g/100g water

Molecular Weight :

144.33

Class/Structure :

HIP polycrystalline cubic, ZnS, F43m

光谱透射曲线：

折射率：（No = Ordinary Ray）

um

No

um

No

um

No

0.54

2.6754

0.58

2.6312

0.62

2.5994

0.66

2.5755

0.7

2.5568

0.74

2.5418

0.78

2.5295

0.82

2.5193

0.86

2.5107

0.90

2.5034

0.94

2.4971

0.98

2.4916

1.0

2.4892

1.4

2.4609

1.8

2.4496

2.2

2.4437

2.6

2.4401

3.0

2.4376

3.4

2.4356

3.8

2.4339

4.2

2.4324

4.6

2.4309

5.0

2.4295

5.4

2.4281

5.8

2.4266

6.2

2.4251

6.6

2.4235

7.0

2.4218

7.4

2.4201

7.8

2.4183

8.2

2.4163

8.6

2.4143

9.0

2.4122

9.4

2.4100

9.8

2.4077

10.2

2.4053

10.6

2.4028

11.0

2.4001

11.4

2.3974

11.8

2.3945

12.2

2.3915

12.6

2.3883

13.0

2.3850

13.4

2.3816

13.8

2.3781

14.2

2.3744

14.6

2.3705

15.0

2.3665

15.4

2.3623

15.8

2.3579

16.2

2.3534

16.6

2.3487

17.0

2.3438

17.4

2.3387

17.8

2.3333

18.2

2.3278

 

 
订购信息：
产品型号：ZNSEPRISM20-BREW

IR Polished Zinc Selenide (ZnSe) brewster angle prism

19.8 x 15 x 10mm brewster angle (67.7°) prism.

产品型号：ZNSEPRISM20-60

IR Polished Zinc Selenide (ZnSe) 60° prism

20 x 20 x 20mm 60° 等边色散棱镜

产品型号：ZNSEPRISM38-30

IR Polished Zinc Selenide (ZnSe) reflecting prism

38 (+0/-2) x 11(±1) x 11mm 120° / 30° / 30° prism

关于晶体切割：

During Chemical Vapour Deposition the small crystallite grains align with the direction of growth, and are normal to the thickness of the sheet produced. For windows of normal thickness and aspect ratios the alignment of the grain therefore is rarely a problem as they are cut from the grown sheet such that within an optical window the grains align perpendicular to the surfaces. This is optimum orientation for lowest internal absorption and scatter.

With prisms, the cutting direction requires more consideration. It is recommended that the thickness of the strip material corresponds to the apex height of the prism. This ensures optimum crystallite orientation for most usual prism applications.

For typical 45° prisms the most obvious use of material is shown in (A) but it should be noted that this is not the optimum orientation.

The best choice is (B) and it also permits a higher limit on prism size or conversely allows thinner stock to be used. There is waste at the ends of the strip but this is small and so it may not be quite as economic as (A).

Cutting in direction (C) where the entire light beam runs at 90° to the grain

structure should be avoided completely if at all possible. Note that maximum available thickness of ZnSe and ZnS (FLIR) is approximately 60mm. Maximum available thickness of ZnS Cleartran is approximately 30mm.